Emulsion co- and terpolymerization of styrene, methyl methacrylate, and methyl acrylate. I. Experimental determination and model prediction of composition drift and microstructure in batch reactions

1996 ◽  
Vol 34 (6) ◽  
pp. 935-947 ◽  
Author(s):  
Harold A. S. Schoonbrood ◽  
Ronald C. P. M. van Eijnatten ◽  
B. van den Reijen ◽  
Alex M. van Herk ◽  
Anton L. German
Keyword(s):  
Methyl Methacrylate ◽  
Experimental Determination ◽  
Model Prediction ◽  
Methyl Acrylate ◽  
Composition Drift

Two-dimensional NMR studies of acrylate copolymers

2009 ◽  
Vol 81 (3) ◽  
pp. 389-415 ◽  
Author(s):  
A. S. Brar ◽  
Ashok Kumar Goyal ◽  
Sunita Hooda
Keyword(s):  
Methyl Methacrylate ◽  
Methyl Acrylate ◽  
Quantum Coherence ◽  
Multiple Bond ◽  
Microstructural Analysis ◽  
2D Nmr ◽  
Correlation Spectroscopy ◽  
Nmr Studies ◽  
Poly Methyl Methacrylate ◽  
Nmr Study

High-resolution NMR spectroscopy is the most versatile, reliable, and generally acceptable technique for the determination of the microstructure of polymers. 2D NMR techniques, along with 1D NMR, have more potential to study absolute configurational assignments and sequence distribution of copolymers. Physical and chemical properties of polymers are influenced fundamentally by their microstructure. We discuss the detailed microstructure analysis of a large number of homopolymers, copolymers, and terpolymers. 2D NMR study of poly(methyl methacrylate) (PMMA), poly(methyl acrylate) (PMA), and poly(methacrylonitrile) (PMAN) is discussed in this article. In addition to homopolymers, 2D heteronuclear single-quantum coherence (HSQC), total correlation spectroscopy (TOCSY), and heteronuclear multiple-bond correlation (HMBC) study of different copolymers such as poly(methyl methacrylate-co-methyl acrylate), poly(styrene-co-methyl methacrylate), and poly(methyl methacrylate-co-methacrylonitrile) have also been reported here. This in turn helps in microstructural analysis of terpolymers such as poly(methacrylonitrile-co-styrene-co-methyl methacrylate), poly(acrylonitrile-co-methyl methacrylate-co-methyl acrylate), and poly(ethylene-co-vinyl acetate-co-carbon monoxide).

Free-radical copolymerization of methyl acrylate with methyl methacrylate in benzene solution

Polymer ◽  
1993 ◽  
Vol 34 (8) ◽  
pp. 1786-1789 ◽  
Author(s):  
C. Arias ◽  
M.M.C. López-González ◽  
M. Fernández-García ◽  
J.M. Barrales-Rienda ◽  
E.L. Madruga
Keyword(s):  
Free Radical ◽  
Methyl Methacrylate ◽  
Methyl Acrylate ◽  
Benzene Solution ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization

Dynamics of adsorbed poly(methyl acrylate) and poly(methyl methacrylate) on silica

2003 ◽  
Vol 281 (3) ◽  
pp. 197-202 ◽  
Author(s):  
Frank D. Blum ◽  
Wuu-Yung Lin ◽  
Crystal E. Porter
Keyword(s):  
Methyl Methacrylate ◽  
Methyl Acrylate ◽  
Poly Methyl Methacrylate
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